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Octopus Manganese Porphyrin with Pol

時(shí)間:2023-04-29 21:18:26 數(shù)理化學(xué)論文

Octopus Manganese Porphyrin with Polyglycol Chains as a Catalyst for the β-Selective Epoxidation of Cholesterol Derivati

Synthesis of a novel octopus porphyrin with polyglycol chains 1a was achieved.The catalytic activity of 1a's manganese complex for the epoxidation of cholesterol derivatives with PhIO give a satisfactory conversion and regioselectivity.

作 者: Run Hua LI Yuan Cong ZHAO Jiang WU Jing Song YOU Xiao Qi YU   作者單位: Department of Chemistry, Sichuan University, Chengdu 610064  刊 名: 中國(guó)化學(xué)快報(bào)(英文版)  ISTIC SCI 英文刊名: CHINESE CHEMICAL LETTERS  年,卷(期): 2004 15(8)  分類號(hào):   關(guān)鍵詞: Octopus porphyrin   synthesis   epoxidation   cholesterol derivatives